We haven't seen a new Enchanter since Nami. Will we ever?
The Enchanter class is sorely needing both a new addition to the roster and a new, modern direction that makes them as interesting as newer flavors of supports. Currently most old enchanters are very generalized designs and have a heavy amount of overlap with one another as well as tending to have issues with counterplay -- which are also issues that force Riot to keep them from ever leaving their place in bot lane.
As much as I dislike the existing enchanter champions I'd really like to see a new one, both just for a change of pace and because I'd love to see a more "modernized" take.
Would my babe count?
Enchanter/Control Mage
Enchanter/Warden
The only to really suck is 
Catcher primary, Enchanter secondary
Diver primary, Enchanter secondary
in there, but I think that's a little bit of a stretch.
and