It's pretty simple. As long as your entire team forms something like a cohesive composition, you'll be fine. It doesn't really matter too much where champions go. Ezreal mid and Vayne top are somewhat normal.
Also, for those who do not know how AD Ahri works, she builds like Ezreal. Muramana->Trinity. She has a few gimmicks.
-She has non-ultimate hard CC, which no other Marksman brings.
-Her super mobility is really strong on a Marksman.
-Her ult and skills all work well with Trinity.
-Most importantly, and the entire reason why she works, is because all three Fox Fire charges apply full Muramana damage because they count as single target spells. This means if you land a charm you get an instant and automatic 4 extra Muramana procs from just Charm+Muramana. Add Trinity proc auto attacks and you burst absurdly hard.
And just like Ezreal, the farther the game goes beyond that 25 minute uber power spike, the weaker she gets in comparison to the late game Marksmen.