If it makes you feel better, if I go Vayne (or any ADC for that matter) I usually do pretty badly :P
I wish I could play Vayne better. I'm not all that bad with dealing with mechanical intensity (after all, I picked up Ori quite well)
I could probably learn how to play her better too, but as with when I picked up Ori, it would take a lot of practice (at least I got to see LCS games with Ori in it, and that helped a lot with the Q-W-E combo), and I started working on playing Vayne, but, with mixed feelings, the Elder Scrolls Online has been my obsession since I got it a week or two ago, and it works a bit better with my environment, where I help my parents in renovating parts of our house (I don't AFK because that'd be breaking the commitment in a League game, but I don't like saying no to my parents). I guess it's something I'll have more time to pick up in a few weeks.
I've been wanting to pick up an ADC for some time now, because I can play other roles with at least average performance, and I've wanted Vayne to be my pick when I go ADC in a draft game (I usually play teambuilder so I don't get much practice). I understand the theory and the mechanics behind playing Vayne too, it's just executing them...I guess just a lot of practice, because she's a hard one, and it took me probably a good 30+ games to pick up Ori, so I just have to practice.
Maybe I'll get to the point where I'm the stereotypical enemy Vayne.
That being said, I hope I don't develop the stereotypical saltiness of Vayne players. I notice when I play Vayne (and Udyr) I get a bit more mad at my teammates (thankfully I don't say anything to them).
Maybe soon I'll be able to roflstomp those enemy ADCs.