can someone post the ranks of all the people on riot's balance team with their most played champs

Hate to break it to you, but how good you are at a game has very little to do with how good you are at balancing said game. For good or bad. Game balancing is an entirely different skillset. Riot's balance team could all be pro-level players and it wouldn't make them any better at balancing the game.

I hear Morello likes annie the most...

Or at least did in season 2