Win-rate isn't a reliable indicator of a champion's strength... on its own. in combination with pick rate, ban rate, and statistics like "picked with" and "picked against", win rate paints a very full picture of a champion's strengths, weaknesses, and percieved strength in the eyes of players.
Sejuani is categorically OP since she has a very high win-rate as well as combined pick and ban rate (her pick rate is only low because she gets banned 75% of all matches). if she had a 55% win rate for a whole year, but only showed up in 3% of matches, you'd know she is very strong in a select few situations. As it stands though, she is good in almost all situations right now, which is why all her statistics are higher than average.
In contrast, we have somebody like Heimer, who has been in the top 15 highest win rates in the game since his rework over a year ago Heimer is no longer OP though, he is just very good against specific champions (kitable/immobile champions with weak early games), which is reflected by his consistently much lower pick rate of between 3 and 4%, and near non existent ban rate, since he is also quite bad in certain matchups.
Lastly, we have Amumu. He has a higher pick rate than Sejuani with an almost identical win rate, but a fractional ban rate. This is because he is a very popular, relatively easy to use champion, but can be countered by somebody with the knowhow to counter jungle and set him behind, which is why his win rate declines the higher rank you look at.