Anyone who would take mobility boots can also consider Swiftness, especially Swiftness with the Alacrity enchant. You roam a bit slower, but you're way faster in-combat.
Champs who need to stick to targets in melee range to be useful can use all the MS they can get. e.g. Udyr, Volibear, Singed. Maybe Trynd, although people tend to go full glass cannon on him with zerker greaves.
Vi and Varus have some extra synergy, since it reduces their self-slows. The slow reduction also stacks with Sejuani's passive slow reduction, and when applied on top of tenacity it makes you very hard to stop.
In general you'd probably look at swiftness boots if you're ahead and can roam/chase frequently -- if you're behind you'll probably want to be tanky.