I think that of all the Ascendants, he can at least empathise with the whole "being a slave" thing, which might colour Aurelion Sol's opinion more positively for Xerath in particular. In terms of power I can see the Ascendants as being comparable to the Aspects, and considering Xerath's ascension brought him closer to the true source of power for that kind of transformation, he might even surpass the Aspects, I mean if we consider that the Aspects are somewhat celestial in their powers and constitution, and Ascension draws upon the power of the Sun, Xerath's arcane might could put him as being closer to that unbelievable cosmic power we see in Aurelion Sol and Bard than the Targonians.
Of course this is speculation; we don't actually know how the Aspects work with celestial power, or how physical they truly are. Is it a Bard situation where they're more or less completely ethereal, or is there some degree of physicality to them, bringing them closer to Soraka? Dunno just yet.