Does Ezreal's Q apply a Rageblade stack?

It also procs Grasp of the Undying.

yes

Well, is a ON-HIT item and 's Mystic Shot (Q) applies on-hit effects, so yes (like what they said above me).

It will apply the damage if you have it fully stacked already, but it will not grant you stacks of Rageblade. That is because Rageblade gains stacks On attack (meaning autos only), but applys extra damage on hit at 8 stacks.