Let's play a game: You name a champion and I(other people are free to help out) assign it a Song
I'm in the mood to share some music and discuss different genres and artists.
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Site with a playlist for every Champion
"And i'll assign a song from the Rock genre" you meant.
Well that kinda narrows it down.
Evil Crackling
might as well just give me his voice over
always playing Party Troll when i pick shaco
######(inb4 Balls to the Wall)
Anyone have a cool song for my main? 
Alright lets see where this goes,
Can I assign vayne a song or would that break the rules?
Well, I have a huge list of champs I main for each role. I don't stick to one specific champion, jack of all trades.
So I'll just list off for each role.
Top 
Mid
Jungle 
ADC 
Supp 
Alistar.