Alistar does best when...
you want to keep harm away from your carry, especially vs "dive in" assassins like kha
Taric does best when...
you want to play a very aggressive botlane, but still want to have the fall back pattern of turtling it out if things go south.
Soraka does best when...
when you want so annoy your opponent till he gets to aggressive and punish him for that. Also when you play certain matchups and need the mana (works well with e.g. urgot and graves), also nice in AoE-Ap teams for the sustained shred
Lulu does best when...
you want to peel for your carry and poke the opponent out of lane early on
Sona does best when...
you can utilze her AoE-speedbuff well, and you have good follow-up on her ultimate or need the AoE counterengage
Jana does best when...
you really want to peel for your carry/reset fights (like e.g. if the opponent has only one engage like a shyvana ->blew her away and poke again or chase)
Thresh does best when...
you play a pick-comp or really need the lantern to keep an immobile adc alive in clashes
Blitzcrank does best when...
you want to snowball hard
Leona does best when...
you want to snowball vs a squishy lane like sona...or if you lack engage in general.
Nami does best when...
you want a really versatile support that can trade well in lane and offers incredible follow up on engages/very good dis-/counterengage
morgana does best when...
you want to block certain abilities like vis ultimate with your black shield to keep you carries from harm
...