Sometimes champions have low win rates not because they are weak but only because they don't fit within the current meta or are played by a lot of people who are bad with the champion. For example, there have been times where champs who are perma picked/banned by the pros have losing win rates in soloq because many people who don't know how to play the champion try to mimic the pros. As for an example of a champion who may be balanced but doesn't fit within the meta, a good example would be Trundle. Trundle used to have one of the highest win rates of any top laner when the meta was to have tanky top laners like shyvanna, Mundo, Renekton, etc. Trundle was an excellent counter for those types of top laners. Now however, the most popular top laners are high damage and most of them are ap, like akali, irelia, jax, ryze, etc. and Trundle just doesn't do as well vs. those types of champs. Maokai is another popular top laner and he is good vs. trundle because he outscales trundle and can sustain enough to not die to him in lane. Trundle doesn't need buffs, or at least not major buffs, he just needs to wait til the meta changes to be more favorable towards him again.