Saying these champs require Master Yi level of skill to play is suggesting that Yi takes a lot of skill to play.
Lucian needs to be able to track his cooldowns and be able to weave his auto attacks in with his spells. Jinx needs to know when to switch her guns, and be able to lane her skillshots. Tristana needs to be able to kite her opponents, especially when her team doesn't peel for her, although Tristana is admittedly relatively easy to play among most ADC's.
I don't think these champs are "toxic", because the term suggests that they have unfair mechanics that make them unfun to play against, while these three champions have mechanics that may be overtuned.
Also, Jinx is by no means a top tiered ADC.