https://leagueoflegends.fandom.com/wiki/Experience_%28summoner%29
^ this will break down your level up rewards. What Dynikus told about predetermined rewards is accurate, the details are on the wiki if your curious.
You can unlock a lot of champions if you spend your BE wisely early on. Just stock pile till you hit 35.
If your super new i recommend you use each and every Free week champions at last once. if you enjoy them spend a few more games and aim to learn a playstyle and/or Buy some champions who teach basic mechanics.
A example
helps give players better map awareness because you can try and guess where enemy champion in fog of war are, then on R cast check your guess vs reality. He also needs to have some decent roam and Mp management can be assisted by using blue cards. To do well on him requires some fundamental skills for the game.