This one is pretty obvious, as Riot's teasers go. The first letters of each champion name spell out XZCLALTH, which is worth 29 points in Scrabble.
20141022 is evenly divisible by 29 (20141022 / 29 = 694518). You can rewrite that as 2014/10/22. 29 is also the number of days in February during a leap year, and the next leap year is in 2016. If you add 2016 to 694518, you get 696534, which only has 8 divisors: 1, 2, 3, 6, 116089, 232178, 348267, and 696534.
You may or may not have noticed at this point that there are 8 champions with "mysterious" champion pages. Of those champions, only 3 have names ending in vowels: Cassiopeia, Lissandra, and Twisted Fate. I have listed them in descending order in terms of the characters in their name (not including spaces): Twisted Fate (11), Cassiopeia (10), Lissandra (9). Being that Cassiopeia and Lissandra are thematically related (once-human women who were transformed after betraying an ally), we can add their numbers (19) and subtract Twisted Fate's (resulting in 8).
Obviously, Riot keep pointing us back to the number 8. Guess how many letters there are in the word "ultimate?" That's right: 8! But given how many times they've thrown the number 8 at us, it can't just be that simple. There are currently 121 champions in League of Legends, and 121 / 8 = 15.125 or 15 remainder 1. When you list all of the champions in alphabetical order from Z-A, the 15th champion is Vi. So Vi will be getting the ultimate skin, but... What about that remainder of 1? If you go one champion further, you get to Vel'koz...
The ultimate skin is going to be Vi with one Vel'koz on each hand, shooting electrical laser punches.
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