If URF was 100% CDR
Who would be the most op champs?
Who would be the most op champs?

Easily Malz. Infinite voidlings. He could win the game before minions even spawn.
would just follow everyone...untargetable
It would be up to who finishes the game first.
are good contestants.
I'd personally have a thing for Azir; since he can use his W on a tower to destroy it and since there are no cd's flash has no cd as well. he could just flashflashflashflash towards the nearest tower and spam W as fast as he can to instantly destroy it, proceed with the next etc. until he takes inhibs, nexus turrets and nexus.

Step 1: Hit level 6 Step 2: Mash R Step 3: Your team is immortal
Behold....
combo.
Tryndamere, infinite ult means always splitting, and since he can cast his ult during cc effects, you really cant stop him
EVERYONE
Everyone.
In every weird thought experiment about zany nonsense with absurd alternate game modes, the answer is always Karthus.
If Tryndamere can get to level 6 with a qss, gg.
Assassins. They have the quickest animations.
Alistar, Taric, etc are good as well.
Taric is invincible and has CC.
Alistar has instant knock-ups, heals, gapclosers, cc cleanse, and DR, as well as a useful passive to tie it all up.
Vlad's another runner-up.
alistar
0cd flash means you better watch your back or it's done for he also has a mean to get rid of cc all the time and takes no damage unless from true damage
and 
aside from malz, heimer and other champs that can summon creeps to take towers befor minions spawn? Vlad, permanent bloodpool, you can't deal damage to him, you can't cc him and sooner or later he drains you dead.
MY SOLDIERS MARCH ON (to keep you in Spawn)
Literally. Never. Stops. Taunting.
I didn't want to play League of Legends today anyway.
CAN'T KILLEAN THE ZILEAN ('s Team)
Literally... Never... Stops... Pooling...
Oh, I'm Sorry, you wanted to play anyone that's not Melee? Too bad.
Literally drags you across the map to his spawn
EDIT:
It would be up to who finishes the game first.
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are good contestants.
100% would be very bad, infinite zhonya etc. Maybe 90% CDR would be intresting.
taric, 100% uptime invuln...

Hi, I'm not even in the game during my Q. It's permanently up. I'm permanently alpha striking.
: unkillable by spamming R
: If she stays out of range, Can kill anyone by spamming R
: Spamming R would never be so fun
: Could potentially stack death marks on targets and instakill virtually any enemy
: Shunpo ult spam anyone? 15% dmg reduction stack anyone?
: Do I really need to explain this one?
taric, perma stun everyone
.
Unless a Karthus is on the enemy team that is, but Karthus has some hard counters in this situation. Even if Azir cannot kill the enemy champions, he can still kill enemy towers with his W as quickly as his finger and computer allow. Also, if this is the same as URF, this also means Zhonya's has no cool down so Azir can just use it every time Karthus uses R since it has a minimum down time equal to the ability's channel. Azir can outdash Fizz as well since Fizz's E has a minimum dash time somewhat since Fizz still has to wait for the dash to end to deal damage. Fizz's Q can also miss if the enemy dashes away or uses Flash if I recall, so Fizz's Q is nearly useless since Flash has no cool down.
would be kinda hilarious to watch. Q > R > Q, Q > R > Q, Q > R > Q, forever until you're dead.
and
would never die. Only reason Kayle doesn't make the cut here is because her ult can't be activated while cc'd.
would be practically untouchable, since there's no limit to the number of plants she can have out (only the number of seeds). Just grow them 4 at a time and you've got an infinite army at your disposal.
would permanently be invisible, with every attack being a 220% damage crit. And woe betide anyone foolish enough to walk into an unwarded bush.
has all of them beat though. Once he hits 6, he can literally just sit in the fountain and spam ult until everyone's dead.
Anyone with an invicibility skill, or Soraka. Hard to kill something that can't die.
qss can counter most cc. If anything, alistar will be most broken. Flash then chain knockup until dead
Kayle no question
behold 

would fire off a never ending chain of stuns and damage, even if
was unkillable he would not be moveing anywhere. Plus at 4 seconds she could fire arrows at other champs every other moment and still have people perma stuned.