Sivir is more like an AD Caster. I believe she has the shortest AA range among Marksmen. Usually after picking up Static Shiv, I can one shot entire waves. Since her attacks bounce, you always attack whatever is closest to you. Tank, minion, whatever. There's nothing in her kit that encourages 1 v 1 fighting.
I enjoy playing Tristana because she can burst down Towers so fast. Because of that, I prefer to be the last person to join a fight. Having a Trist survive a team fight is almost guaranteeing a tower or dragon goes down. She doesn't feel like a strong duelist at any stage of the game, though she does have excellent clean up tools with W resets. This is mostly because her E is delayed and her R is better for peel than engage.
The fact that neither of these are duelists could be an issue with the present META. Just keep that in mind when playing them. You don't want 1 v 1 or random picks with these two.