Aatrox + devourer doesn't proc Aatrox W (At All)
Here's a conversation between me and my friend that explains the situation pretty well.
[4:29] Willo: i got trolled by devourer ina 1v3 my W wasn't healing me as aatrox [4:29] TheLolo: lool [4:29] Willo: Cause Devourer was proccing my 3rd hit instead of letting me do my third it so it was skipping it [4:30] TheLolo: is that a bug? [4:31] Willo: I think so. but you can surpass it For example, devourer has like a 4 second "succesion" timer ( not sure of correct duration) so unless you auto within 4 seconds or something, it won't proc devourer however with aatrox, his W does not have a timer so you could hit a tower, and 30 seconds later, hit a minion twice and the third hit will heal you so what you have to do is actually auto attack something,' wait for devourer to reset then you can go to town with AUTO HEAL AUTO HEAL because then every 2nd hit will be devourer rather than the 3rd I think it's a bug but I'll post it
RECAP
This is a really good explanation of how to do it and how to get around it, however I'm not sure if this is intended or not.