Pyke's ult executes enemies even if they have GA.
Or at least it does on Nexus Blitz. We won a late game snowball fight, got GA's for the team, and decided to take a 5v5 teamfight. Pyke proceeded to get 4 kills with his ult that teamfight because, mysteriously, his ult would bypass GA and give him the kill anyway.
can ignore it using his Ultimate [R: Death from Below]. Given the circumstances, Urgots
Ultimate [R: Fear Beyond Death] might also be another one to consider since he can execute you too.