I believe that Yordles have a slightly shorter lifespan than humans, not much, but noticeable, perhaps a few years less, decade at most. Champion ages have been left vague, something I suspect is intentional to promote greater speculation on behalf of the players.
In so far as I am concerned, the Yordles all seem to be young adult to old with Gnar being the only exception.
: Somewhere between young adult and middle-aged - 18 or 30, it is difficult to say; he was considered old enough for long-term employment with traveling merchants, so I suspect he was of working age and capable of living independent of his immediate family, if he had any. His lack of physical features and insanity make pinpointing age difficult.
: Adult to middle-aged - possibly 25 and up. Teemo is a veteran, a scout more specifically, and I doubt his status is easy to come by in someone of a younger generation. Sure, he sounds young, but I doubt anyone would last long in his position without substantial experience.
: Young adult to adult - between 20 and 30. Rumble is an accomplished mechanic who has built a fairly impressive machine from what amounts to junkyard scrap. However, he is rather hot-headed, overconfident, and more than a little insecure, hallmarks of youth if I have ever seen any.
: Middle-aged to old; perhaps the rough equivalent to 40-60 years. The Revered Inventor, Heimerdinger has attained notoriety among not just Bandle City, but Piltover as well. His thick fur and large mustache advertise his obvious maturity, not to mention a wicked hairstyle.
: Young adult; definitely at a point between 18 and 25 years of age. Gung-ho, flippant, and utterly indomitable attitude practically scream "I AM YOUNG AND HAVING THE TIME OF MY LIFE". For her line of work, a gunner, she seems disturbingly upbeat, which can only lead me to suspect she lacks the same battlefield experience Teemo has acquired.
I would post more, but it is dinnertime and I am hungry. Just my headcanon - don't touch, it may explode.