Highest DPS is a tough thing, it needs to include type of damage, rate of damage, target swap ease, and the safety.
Type of damage means that if you do only physical damage (hi Draven), armor beats you up hard. Magic damage is not affected by armor, so corki beats high armor targets, for example.
Rate of damage is attack speed OR how often you can use your main spell, if you have one.
target swapping is changing targets of higher priority than the current target, vayne has a hard time doing this as it destroys her DPS.
Safety is both how fast you can move, AND how reliably you can kite opponents back.
If you want the pure unbridled highest DPS in the game, it is a very very close thing.
I'll do a bit of research on it though, using level 1 max DPS, 3 item DPS(taken by highest winrates builds), and 6 item DPS.
This'll take a while XD