Twisted Fate's W does not proc on inhibitors or the nexus.
Using
Twisted Fate's W on an inhibitor or a nexus doesn't proc it, similar to how it doesn't proc on plants, or how Rek'Sai's q doesn't proc on any building. Not sure if Riot would want that considering it works on turrets, and considering that his w isn't nearly as powerful on buildings as say
Ziggs' W, I'd consider this unintentional.