Can't ult Zac as Skarner.
I've seen a few posts over on the league subreddit about this and just had it happen directly to me. I was playing Skarner (using the Battlecast skin if that matters) and ult'd the enemy Zac (default skin) and my ult went on CD and Zac just walked away. These champs aren't exactly in every game but assuming it doesn't work on 1 champ it may not work on others and it's frustrating regardless.
ult