You need to be within 550 units of a visible enemy champion in order to ignore unit collision, and it doesn't look like you were within 550 units of Vayne while you were being creep blocked. For reference, Vaynes AA range is 550, so if she can't auto attack you, then you won't ignore unit collision.
EDIT: After some searching, you actually need to be within 500 units of a visible enemy champion to ignore unit collision, as per patch 5.22, and it hasn't been raised to 550 at all since. This is a bug with tooltip giving the incorrect unit amount.
This means that if Vayne is auto attacking at her max range, you still wouldn't be able to ignore unit collision.