Ahri Charm {{champion:103}}
This happened a few times, against different champions. First, Leblanc used her distortion towards me, and I hit her with charm. Leblanc took damage, but was not CCd and was able to press W again to safety. Another champion something similar happened was Xin Zhou. As he used his gap closer, I landed my charm (happened twice in the same game). He was not affected by the CC.
Lastly, not sure if this is intentional or not, but I charmed Teemo before I died. He was affected by the CC. However, right when I died, the CC of charm ended (it ended earlier than if I was alive). Not sure if champs are still charmed by dead bodies (necrophelia)