You cannot use Shiv's passive on Diana basics. http://matchhistory.na.leagueoflegends.com/en/#match-details/NA1/2109691275/222758586?tab=overview I tried to use it several times on minions and on champions and it never worked.
BlueBonquet1 votesWhy does Diana have statikshiv?
Nanuk Pihoqahiak1 votesWhy does it matter? It's obviously a bug.
NazZomLord1 votesWhy does Diana have statikshiv?
Idk, AD Diana?
Mama Soraka1 votesThere has been some discussion about Diana and items that build from 
in this thread: Diana cannot proc energized strike