To be honest, now is probably the worst time to ask for advice on playing Vladimir because he literally just got a rework. He hasn't really changed all that much so you can get some advice, but what is ultimately "best" is probably not certain at this point. Even one of his most core items Will of the Ancients, has just been completely removed from the game.
That said, I will do my best. As far as items go, most people would probably agree that building AP works better with his passive than building health. You will be able to deal a greater amount of damage while remaining tanky enough to have decent survivability.
are good because they provide both. Rylai's slow is very useful, and Liandry's magic pen and burn is great when you take him to the top lane against tanks.
actually becomes more efficient than it is with other mages.
is a good source of AP and magic pen as he has a pretty low range on his abilities.
is great on the flip side because his kit is pretty heavily focused on being able to heal himself.
is another example of things that I don't really know much about, but it looks like a really good item on him because it gives health, AP, and CDR.
<Quick note about CDR, while it is good, you want to be careful. With your Health being your resource, too much CDR and not enough ability to regain a significant amount of health back, means you will pretty much be killing yourself>
As for boots, take your pick between
depending on your situation
are useless because you most likely wont be relying on your auto attacks for anything.
&
are always something to consider as a form of movement speed (they are boots after all) but Vladimir isn't often a big roamer. His lack of built in mobility will make any movement speed useful still.
As for your level. I will say that I have to agree with your consideration of being new. That isn't to say anything about your skill, just that this game is quite extensive. I am still learning and I've been level 30 forever. The fact that things continue to change on a nearly weekly basis makes it impossible to learn everything, and that is one of the best things about this game in my opinion. Stick with it and stay open to learning new strategies without letting losses get to you, and you should be just fine. But most importantly, have fun. This is a video game.