You want a character that is simple or that you already know well so that you can practice all of the mechanics necessary to play well as a marksman. As such you want to avoid marksmen with weird gimmicks or unusual playstyles, as they will not play like other marksmen. Jhin for example is lots of fun, and really cool, but he doesn't play like any other marksman. So you wouldn't want to try to learn the role by playing him.
Some of the mechanics that you will need to master are, positioning, attack-move, build flexibility, lane management, trading and last hitting.
Ashe, Misfortune, Varus and Jinx are all immobile marksmen, requiring you to learn positioning and attack-move in order to use safely and effectively. The other mechanics can be learned on any champion.
You're best off picking one or two to main and just playing them consistently while you master the mechanics. Additionally you will learn faster if you make use of video guides like the video linked here:
https://www.youtube.com/watch?v=cGliAuBBcP4
Their channel also has detailed guides on specific champions, so you may be able to find something for a specific champion you want to play.