Thats stupid. Like, really stupid. What you're really looking for is of you don't use spells in X amount of time, but this broken as all hell.
Mana is a gating mechanic, you're basically trying to remove it without removing it. If you want something that that makes Athenes "worthwhile" then you'd want something along the lines of a harassment mechanic like:
Mana Font: Whenever you damage a Champion with a Spell, your Mana Regen increases between 50% to 400% depending on percentage of missing mana
Effectively turning Athenes into the Harassment item, allowing mages to negate Mana issues if they are consistent in their harassment of their lane instead of a sit back and Regen. It may have to suffer by giving no Regen otherwise (forcing you to constantly use your spells to harass), but we can't just make Athenes overtake Morellos just because.
Hell, I'd even be happy making Athenes an absorption item with stacks or something attached to it:
Mana Drink:
Passive: Every few seconds Athenes gains a Concentration stack. Whenever you Basic Attack or Damage a Champion with a spell gain X stacks
Active: Consume stacks, Gain X Percent of mana